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Once the plaster Mother mold has been opened, you can easily remove the Silicone mold from it. Simply peel the two halves apart carefully, especially around areas like the mouth and hands as you don't want to accidentally pop off silicone for those detail areas.
Sadly, if you did the sculpt in Super Sculpey, the original will probably get cracked and broken. But the whole point of this is to make new, flawless copies!!